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Preheat oven to 350 degrees Fahrenheit.
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Sift flour, 1 cup sugar, 1/3 cup cocoa powder, baking soda and salt into an 8" square pan.
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Make three 2" holes in flour mixture with fork.
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Pour warm water and 1 teaspoon vanilla into 1 hole.
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Pour vegetable oil into the second hole.
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Pour vinegar into the third hole.
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Stir through batter until well mixed, 1-2 minutes.
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Bake until toothpick inserted in center comes out clean, about 30 minutes.
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Cool cake completely in pan.
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For the icing, combine remaining 1/2 cup sugar, butter, milk, and 2 tablespoons cocoa powder in small saucepan over medium heat and bring to boil.
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Reduce heat and simmer 1 minute.
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Remove from heat and stir until cool, about 5 minutes.
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Add remaining 2 teaspoons vanilla and mix well.
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Spread icing over cake in pan.
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Let cool until set.