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Prepare rice according to package directions; keep warm.
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Put skillet over med-high heat until hot; add sesame seeds; cook, stirring constantly, 3-4 minutes or until seeds are toasted; remove seeds from skillet.
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Cut chicken into 1-inch pieces; combine chicken and cornstarch, tossing to coat.
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Heat olive oil in skillet over med-high heat.
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Cook chicken about 5 minutes on each side or until done.
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Decrease heat to medium, and stir in pineapple juice and the next 3 ingredients; bring to a boil and cook, stirring occasionally, 1 minute or until thickened; remove skillet from heat.
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Remove chicken mixture to a serving platter; sprinkle with toasted sesame seeds and chopped green onions; serve with warm rice.