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Lightly grease the inside of a 4-quart saucepan.
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Line a baking sheet with waxed paper.
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Stir the brown sugar, white sugar, baking soda, sour cream, and corn syrup together in the oiled pan; place over low heat.
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Cook and stir continually until the sugars are dissolved.
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Wipe any sugar crystals above the liquid line with a pastry brush moistened with cold water.
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Bring to a boil over medium-high heat.
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Do not stir once the sugar syrup begins to boil.
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Heat to 240 degrees F (115 degrees C), or until a small amount of syrup dropped into cold water forms a soft ball that flattens when removed from the water and placed on a flat surface.
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Remove from heat; stir in the butter, vanilla, and chopped pecans.
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Drop spoonfuls of the mixture 2 inches apart onto the prepared baking sheets.
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Press a pecan half into the top of each praline.
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Allow to cool completely.
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Store in an airtight container in a cool place.