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Preheat oven to 375 degrees.
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Line two standard-size muffin pans with baking cup liners.
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In a bowl whisk together the cake flour, salt, cocoa, and baking powder to combine.
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In a pitcher, whisk together the buttermilk, food coloring and vanilla until blended.
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In a standard mixer set on medium to medium-high speed, beat the butter and sugar until light and fluffy, about 5 minuted.
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Add the eggs, one at a time. Beating until fully incorporated; scrape down the sides and bottom of bowl as necessary.
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Add the flour mixture in portions, alternating with the buttermilk mixture until smooth and just blended.
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In a cup combine the vinegar and baking soda, allow to fizz, then fold into the batter by hand.
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Working quickly divide the batter evenly among the muffin pan cups and place into the oven immediately.
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Bake for 15 minutes, then check center of the cupcakes with a toothpick. If you have a few crumbs clinging to the toothpick the cupcakes are done. If the toothpick comes out with more than a few crumbs, return to the oven for a minute or so, watching closely.
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Cool cupcakes in pan on a wire rack until cool enough to handle, about 15 minutes. Carefully lift each from the pan, and set on the wire rack.
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Cool to room temperature before icing, about 30 minutes.