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In a microwave or double boiler, melt chocolate chips and shortening. Chill for 15-20 minutes until thickened.
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Line a 9 inch square baking pan with foil making sure that the foil extends over the sides of the pan. Grease the foil in the pan and set aside.
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In a saucepan over low heat, melt butter. Stir in marshmallows and butterscotch chips until melted and smooth.
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Place the popcorn in a large bowl; add marshmallow mixture and toss until coated.
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Firmly press half of the popcorn mixture into prepared pan. Spread chocolate mixture evenly over popcorn. Firmly press remaining popcorn mixture over chocolate.
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Chill for 30 minutes. Lift out of pan using foil edges that are extended over the sides. Remove foil. Cut into bars.