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Before starting prepare a cookie sheet or silpat sheet with a very light coating of vegetable oil cooking spray.
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Set up a double boiler with hot water just barely at a simmer. Place the top half of the boiler on top and add two thirds of the chocolate chips.
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Stirring regularly, melt the chips for a minute or two until the chocolate is smooth. Don't let the chocolate get too hot or it will need to be tempered again.
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Once the chocolate is smooth and glossy, add the remaining third of the chips and stir for 20 seconds.
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Add in the walnut pieces and orange peel. Stir just until mixed.
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Pour out the chocolate onto the prepared sheet and allow it to fully cool. The thickness is a matter of personal preference.
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Break the bark into pieces and enjoy.