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To make the cake, preheat the oven to 350 degrees F.
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Grease and flour a Bundt cake pan.
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Beat the butter with the sugar in a separate bowl until fluffy.
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Beat in the eggs, one at a time.
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Stir the flour with the baking powder and salt until combined.
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Whisk the milk with the vanilla and espresso powder.
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On low speed, alternately beat the flour and milk mixtures into the butter mixture.
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Stir in the chocolate chips and scrape the batter into the pan.
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Bake for 45 to 55 minutes or until a tester inserted comes out clean.
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Cool in the pan for 10 minutes, then finish cooling on a rack.
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To make the glaze, heat the chocolate chips, butter, syrup and espresso powder in a saucepan set over medium heat.
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Cook, stirring constantly, until glossy and smooth.
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Drizzle over the cooled cake.
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Let stand until the glaze is set.